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Inorganic and organic chemistry

7 ECAT Chemistry questions with answers and explanations.

All questions with answers
  1. What is the shape of the SF6 molecule?

    • 1 Tetrahedral
    • 2 Octahedral
    • 3 Trigonal bipyramidal
    • 4 Square planar
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    Correct answer: Octahedral

    Sulphur has six bond pairs and no lone pairs, which gives an octahedral shape.

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  2. Which catalyst is used in the Haber process for making ammonia?

    • 1 Nickel
    • 2 Platinum
    • 3 Iron
    • 4 Vanadium pentoxide
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    Correct answer: Iron

    Finely divided iron is the catalyst in the Haber process. Vanadium pentoxide is used in the Contact process.

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  3. Which reagent distinguishes an aldehyde from a ketone?

    • 1 Bromine water
    • 2 Tollens' reagent
    • 3 Lime water
    • 4 Litmus paper
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    Correct answer: Tollens' reagent

    Aldehydes reduce Tollens' reagent to give a silver mirror. Ketones do not.

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  4. According to Markovnikov's rule, the addition of HBr to propene gives mainly:

    • 1 1-bromopropane
    • 2 2-bromopropane
    • 3 Propane
    • 4 1,2-dibromopropane
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    Correct answer: 2-bromopropane

    The hydrogen goes to the carbon that already has more hydrogens, so bromine ends up on the middle carbon.

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  5. Which type of alkyl halide reacts fastest by the SN1 mechanism?

    • 1 Methyl
    • 2 Primary
    • 3 Secondary
    • 4 Tertiary
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    Correct answer: Tertiary

    A tertiary carbocation is the most stable, so tertiary halides react fastest by SN1.

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  6. What is the product when ethene reacts with steam in the presence of an acid catalyst?

    • 1 Ethanal
    • 2 Ethane
    • 3 Ethanoic acid
    • 4 Ethanol
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    Correct answer: Ethanol

    Acid-catalysed hydration of ethene adds water across the double bond to give ethanol.

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  7. What is the hybridisation of sulphur in SF6?

    • 1 sp3
    • 2 sp3d
    • 3 sp3d2
    • 4 sp2
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    Correct answer: sp3d2

    Six bond pairs need six hybrid orbitals, which use one s, three p and two d orbitals.

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