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7 ECAT Chemistry questions with answers and explanations.
What is the shape of the SF6 molecule?
Correct answer: Octahedral
Sulphur has six bond pairs and no lone pairs, which gives an octahedral shape.
Which catalyst is used in the Haber process for making ammonia?
Correct answer: Iron
Finely divided iron is the catalyst in the Haber process. Vanadium pentoxide is used in the Contact process.
Which reagent distinguishes an aldehyde from a ketone?
Correct answer: Tollens' reagent
Aldehydes reduce Tollens' reagent to give a silver mirror. Ketones do not.
According to Markovnikov's rule, the addition of HBr to propene gives mainly:
Correct answer: 2-bromopropane
The hydrogen goes to the carbon that already has more hydrogens, so bromine ends up on the middle carbon.
Which type of alkyl halide reacts fastest by the SN1 mechanism?
Correct answer: Tertiary
A tertiary carbocation is the most stable, so tertiary halides react fastest by SN1.
What is the product when ethene reacts with steam in the presence of an acid catalyst?
Correct answer: Ethanol
Acid-catalysed hydration of ethene adds water across the double bond to give ethanol.
What is the hybridisation of sulphur in SF6?
Correct answer: sp3d2
Six bond pairs need six hybrid orbitals, which use one s, three p and two d orbitals.