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Solutions, equilibrium and kinetics

8 NET Chemistry questions with answers and explanations.

All questions with answers
  1. How many atoms are there in exactly 12 g of carbon-12?

    • 1 6.022 x 10^23
    • 2 12 x 6.022 x 10^23
    • 3 3.011 x 10^23
    • 4 6.022 x 10^22
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    Correct answer: 6.022 x 10^23

    12 g of carbon-12 is one mole, which contains Avogadro's number of atoms, 6.022 x 10^23.

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  2. What is the molarity of a solution containing 98 g of H2SO4 in 1 litre of solution? (H = 1, S = 32, O = 16)

    • 1 0.5 M
    • 2 2 M
    • 3 98 M
    • 4 1 M
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    Correct answer: 1 M

    The molar mass of H2SO4 is 98 g/mol, so 98 g is 1 mole. In 1 litre this is 1 M.

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  3. The elevation of the boiling point of a solution is proportional to its:

    • 1 Molality
    • 2 Density
    • 3 Volume
    • 4 Colour
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    Correct answer: Molality

    Boiling point elevation is a colligative property: delta Tb = Kb x molality.

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  4. For N2 + 3H2 <-> 2NH3, the relation Kp = Kc (RT)^n has n equal to:

    • 1 -2
    • 2 2
    • 3 -4
    • 4 4
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    Correct answer: -2

    n is the change in moles of gas: 2 - (1 + 3) = -2.

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  5. The forward reaction of an equilibrium is exothermic. Raising the temperature will:

    • 1 Shift the equilibrium to the right
    • 2 Shift the equilibrium to the left
    • 3 Have no effect on the equilibrium
    • 4 Double the equilibrium constant
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    Correct answer: Shift the equilibrium to the left

    According to Le Chatelier's principle, the system opposes the added heat by favouring the endothermic, reverse reaction.

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  6. For a first order reaction, doubling the concentration of the reactant makes the rate:

    • 1 Double
    • 2 Four times as large
    • 3 Stay the same
    • 4 Halve
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    Correct answer: Double

    Rate = k[A], so the rate is directly proportional to concentration.

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  7. What is the pH of 0.1 M NaOH at 25 degrees C?

    • 1 1
    • 2 13
    • 3 12
    • 4 14
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    Correct answer: 13

    [OH-] = 0.1, so pOH = 1 and pH = 14 - 1 = 13.

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  8. Which of these is a Lewis acid?

    • 1 NH3
    • 2 H2O
    • 3 BF3
    • 4 OH-
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    Correct answer: BF3

    BF3 has an empty orbital on boron and accepts an electron pair, so it is a Lewis acid.

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